Download Carbon-Rich Compounds - From Molecules to Materials by Henning Hopf PDF

By Henning Hopf

The 2 uncomplicated construction devices carbon and hydrogen will be mixed in one million alternative ways to offer a plethora of interesting natural compounds. Henning Hopf provides not just the main impressive constructions and homes of hydrocarbon compounds yet indicates in a transparent presentation and with nice didactic ability how molecules like dodecahedrane, superphane or annulenes problem the factitious abilities of each natural chemist. To make the data extra available, in particular to the amateur, the writer rigorously analyzes the substitute challenge, explains every one artificial step and provides tricks on substitute equipment and strength pitfalls. various references to important studies and the unique literature make this publication an imperative resource of extra details. targeted emphasis is put on the skillful use of pictures and schemes: man made (retro)analyses, response sequences, and the most important steps are awarded in blue boxed sections in the textual content. Graduate scholars and researchers alike will locate this publication a gold mine of helpful details crucial for his or her day-by-day paintings. each natural chemist may want to have a duplicate on his or her table. With a foreword by way of W. von Eggers Doering.

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Siebert, Ber. Dtsch. Chem. Ges. 1906, 39, 1024–1035. R. Scholl, C. Seer, R. Weitzenbo¨ck, Ber. Dtsch. Chem. Ges. 1910, 43, 2202– 2209. ¨ ck, Monatsh. Chem. R. Weitzenbo 1913, 34, 193–223. (a) K. Dziewon´ski, Ber. Dtsch. Chem. Ges. 1903, 36, 962–971; (b) P. Rehla¨nder, Ber. Dtsch. Chem. Ges. 1903, 36, 1583–1587. K. Dziewon´ski, S. Suknarowski, Ber. Dtsch. Chem. Ges. 1918, 51, 457–465. C. Moureu, C. Dufraisse, P. M. Dean, C. R. Acad. , Paris 1926, 182, 1440–1443. (a) C. Moureu, C. Dufraisse, G. Berchet, C.

Marschalk, Bull. Soc. Chim. Fr. 1939, 6, 1112– 1121, 1122–1125. W. J. -W. Liao, J. Am. Chem. Soc. 1955, 77, 992–993. (a) C. Marschalk, Bull. Soc. Chim. Fr. 1938, 5, 306–308; 1941, 8, 354–369; 1950, 16, 311–317. R. Scholl, K. Meyer, Ber. Dtsch. Chem. Ges. 1932, 65, 902–915. (a) R. Scholl, J. Mansfeld, Ber. Dtsch. Chem. Ges. 1910, 43, 1734– 1746; (b) R. Scholl, K. Meyer, Ber. Dtsch. Chem. Ges. 1934, 67, 1236– 1238. W. C. Lothrop, J. Am. Chem. Soc. 1941, 63, 1187–1191. (a) G. Wittig, H. F. Ebel, Liebigs Ann.

11). It is important to note that all the parameters needed to calculate kF with good precision can be obtained from independent measurements. The only real uncertainty relates to estimating R for flexibly linked dyads. In the context of designing molecular-scale wires, the Dexter mechanism is more relevant since it provides direct information on the propensity of the connector to conduct electrons. This mechanism involves the simultaneous transfer of an electron, by way of bridging LUMOs, and a positive hole, via the bridging HOMOs, from donor to acceptor [102].

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