By G.R. Newkome
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Additional info for Advances in Dendritic Macromolecules : 1995 (Advances in Dendritic Macromolecules) (Advances in Dendritic Macromolecules)
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Soc. 1993,775,11496. 24. Newkome, G. ; Moorefield, C. ; Baker, G. ; Johnson, A. ; Behera, R. K. Angew. Chem. Int. Ed. Engl. 1991,30, 1176. 25. Hawker, C. ; Wooley, K. ; Frechet, J. M. J. J. Chem. Soc, Perkin Trans. 11993, 1287. 26. (a) Newkome, G. ; Young, J. ; Baker, G. ; Potter, R. ; Weis, C. , C. S. Macromolecules 1993,26, 2394; (b) Newkome, G. ; Moorefield, C. ; Baker, G. ; Saunders, M. ; Grossman, S. H. Angew. Chem. Int. Ed. Engl. 1991,30, 1178. 27. Hawker, C. ; Frechet, J. M. J. J. Chem. Soc, Perkin Trans.
By employing different multidirectional core units, the procedure is generalized. The first X-ray structure of a first-generation cascade molecule is presented, and its photoswitching azobenzene derivate demonstrates reversible (£)/(Z)-isomerization. The pursuit of our cascadelike polyamine synthesis, developed in 1978,^ is achieved with an improved reduction method. The resulting amines are converted into imines that can complex transition metals. Crown compounds based on "Hexacyclen" and "Cyclam" as core units represent another type of potential complexing dendrimer.